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Image may contain Anne Hathaway Human Person Red Carpet Fashion Red Carpet Premiere Premiere Tie and Accessories

Anne Hathaway and Valentino Garavani at the Oscars, 2011.Photo: John Shearer / Getty Images

Image may contain Julia Roberts Clothing Apparel Human Person Evening Dress Fashion Gown Robe Plant and Flower

Oscar-winner Julia Roberts in Valentino, 2001.Photo: Frank Trapper / Corbis via Getty Images 

Image may contain Ben Affleck Tie Accessories Accessory Human Person Fashion Premiere Suit Coat and Clothing

Jennifer Lopez, in Valentino, with Ben Affleck at the Academy Awards, 2003.Photo: Frank Trapper / Corbis via Getty Images

Image may contain Human Person Dance Pose Leisure Activities Sunglasses Accessories Accessory Footwear and Clothing

Valentino Garavani and Jacqueline Kennedy, 1970.Photo: Bettmann

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